07/06/2021
SEPARATING LIQUID/LIQUID MIXTURES
Oil and water do not mix easily. They are said to be immiscible
1.LIQUIDS WHICH ARE MISCIBLE
If miscible liquids are to be separated, then this can be done by fractional distillation. Fractional distillation relies upon the liquids having different boiling points. When an ethanol and water mixture is heated,the vapours of ethanol and water boil off at different temperatures and can be condensed and collected separately. Ethanol boils at 78 °C whereas water boils at 100 °C. When the mixture is heated the vapour produced is mainly ethanol with some steam. Because water has the higher boiling point of the two, it condenses out from the mixture with ethanol. This is what takes place in the fractionating column. :The water condenses and drips back into the flask while the ethanol vapour moves up the column and into the condenser, where it condenses into liquid ethanol and is collected in the receiving flask as the distillate. When all the ethanol has distilled over, the temperature reading on the thermometer rises steadily to 100 °C, showing that the steam is now entering the condenser. At this point the receiver can be changed and the condensing water can now be collected.
2.LIQUIDS WHICH ARE IMMISCIBLE
If two liquids are immiscible they can be separated using a separating funnel. The mixture is poured into the funnel and the layers allowed to separate...The lower layer can then be run off by opening the tap.