30/06/2020
CHEMISTRY THIS WEEK ON FACEBOOK
Dear Facebook followers, our lesson this week is for S.S 2 students. However, other classes and older followers can refresh their knowledge.
TOPIC : ELECTROLYSIS (for beginners)
Some students are always afraid of the topic electrolysis, thinking its too difficult to understand 🙄🤔🥴.
But don't worry you all will have a clear understanding of it.
Electrolysis deals with the use of electric current to make a chemical reaction take place.
To understand electrolysis we must know the following;
1. Standard electrode potential: the standard electrode potential of a metal is the potential difference between the metal and one-molar solution of its ions at 25°C.
Explanations; we have two charges, positive (+) and negative (-). And an electron carry a negative charge which is represented as e- . potential difference is the work done in moving a charge from one place to another. And is measured in volt.
Look at NaCl, we understand that Na has 11 electrons as 2, 8, 1.
Before Na joins (react) with Cl, Na must give that last 1 electron to Cl to form ionic bond. Thus that 1 electron has to move from Na to Cl, and since the electron has a charge, we say the work done as the electron leaves Na to stay with Cl is the potential difference which is regarded as the standard electrode potential.
All ions have their different standard electrode potential.
How do we get the standard electrode potential of an ion?🤔🤔🤔🤔
Its easy, you can get it through experiment using an electrochemical cell set up. Two beakers are always used , one holds the electrode and the metal and the other holds hydrogen ion and hydrogen gas with an electrode and a salt bridge that connects the two beakers and a voltmeter to read the potential difference known as the standard electrode potential.
All scientists have agreed that hydrogen ion (H+) should be given a standard electrode potential of 0 volt at all temperatures. Therefore standard electrode potential is always measured in the presence of Hydrogen ion and Hydrogen gas in one of the beakers.
That is , if I want to find the standard electrode potential of Cu+, then one beaker will have Cu+ and the other must have H+ and hydrogen gas.
During the process electrons move, and as electron move , the voltmeter calculates the potential difference which is taken as the standard electrode potential.
The standard electrode potential can be positive (+) or negative (-) .
How do we know if an ion will have a negative or positive standard electrode potential value ( number)?🤔🤔🤔🤔😒
Its simple , 😱 during the experiment, the voltmeter has a needle that moves and tells you the place where the electron leaves and where it goes, so if the needle points at the side where the metal is, the electrode potential is taken to be negative (-). Example, if the needle points at the side where Cu²+ is and the voltmeter has a value 0.34 volt, it means the standard electrode potential of Cu²+ is +0.34 volt and means electrons travel from the side of H+ /H2 gas to the side of the Cu²+.
And if the needle points at the side of the H+ / H2 gas, then , it means electron moves from Cu²+ to the side of H+ / H2 gas and therefore the standard electrode potential will be taken as -0.34 volt.
2. ELECTROCHEMICAL SERIES: experiment has already been done and the standard electrode potential of all ions are recorded. And from mathematics we understand that a positive number is bigger than a negative number . example +1 is bigger than -1 ,
0 is bigger than -1.
Thus an electrochemical series is a chart that gives the standard electrode potential of ions and their order of reactivity.
😱😱😱
The most reactive metal ion has the smallest standard electrode potential.
ION. STANDARD ELECTRODE POTENTIAL
K+. ----->. -2.92 volt
Ca²+ -----> -2.87 volt
Na+ ------>.-2.71 volt
Mg²+ ---> - 2.37 volt
Al³+ -----> -1.66 volt
Zn²+ -----> -0.76 volt
Fe²+ ------> -0.44 volt
H+ ---------> 0.00 volt
3. REACTIONS: To understand electrolysis you must know what each reaction mean.
Remember I told you that e- means an electron, therefore ;
e- = 1 electron
2e- = 2 electrons
3e- = 3 electrons
4e- = 4 electrons
etc.
Easy right ???🤞🤞🤞
We understand that when writing a chemical reaction equation, anything on your left Hand side is the reactant and anything on your right hand side is the product.
Let's understand some equations
1. Na ---> Na+ + e-
At the left , it means 1 electron has left solid Na atom to give you the ion Na+ at right as the product.
Wow...
Since you started with Na at the left and it was not having a charge, but ended with Na+ which had a charge +1 at right, we say the reaction is an OXIDATION reaction.
So any time the product ends up with a positive charge , we call it an oxidation
2. Ca ---> Ca²+ 2e-
This also means Ca has removed 2 electrons from it to become Ca²+. So since we started with Ca at the left hand and ended with Ca²+ we call the reaction an OXIDATION. Because the oxidation state increased from zero (0) to +2.
Note: all neutral atoms have a zero oxidation state. This means all atoms with no charge have zero oxidation state.
How can I know that an atom can loss a particular number of electrons?
The number of electrons lost are equal to the valency of the atom.
HOWEVER, if we exchange the position of the reactants and products it will change the meaning as well as shown below👇
1. Na+ + e- ---> Na
Here it means Na+ gains 1 electron to become Na. We started with Na+ at left which has a +1 charge and ended up with Na at right which has zero charge, because the charge reduced from +1 to 0 , we say the reaction is a REDUCTION reaction.
Same applies to ;
2. Ca²+. + 2e- ---> Ca
We shall make use of this in electrolysis and determine the half reactions at the anode and cathode and from there write the overall reaction without a problem.
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4. DISPLACEMENT / DISCHARGE OF IONS: Displacement simply means the ability of an ion to remove another ion of the same charge in compounds.
Examples, if we have a compound like HCl, and when F- removes Cl from HCl to give a new compound HF , we say F has displaced or discharged Cl- from the compound.
How can we know which ion will displace another ion in a given compound.? 😓😨🥱
Its simple, we make use of the standard electrode potential we learnt and the electrochemical series. All the metal ions that have smaller standard electrode potential and are up will always displace the metal ions below it.
Here's the order for some metal ions :
K+
Ca²+
Na+
Mg²+
Al³+
Zn²+
Fe²+
Sn²+
Pb²+
H+
Cu²+
Ag+
Therefore a metal up can remove a metal down from a compound (displacement). And occupy the position.
Examples
1. 2Na + can remove 2H+ in H2S04 👇
H2SO4 + 2Na---> Na2SO4
But 2H+ can not remove 2Na+ from Na2SO4👇
Na2SO4 + H2 ---> H2SO4
This one is wrong. 🤥🤥🤥 never do it.
However, Ca²+ is above Na+ , but Na+ is more reactive because the big Ca²+ has a higher ionization energy due to greater nuclear charge effect than the small Na+.
Same thing applies to anions
F-
SO4²-
NO3-
Cl-
Br-
I-
OH-
All the ones up will displace the ones down.
We shall continue from here next week. Till then, remember CHEMISTRY IS SIMPLE!