Biomimetic Inorganic-Organic Coordination Chemistry, UNIST

Biomimetic Inorganic-Organic Coordination Chemistry, UNIST

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울산과학기술원 화학과 생체모방 유무기 배위화학 연구실(지도교수 : 조재?

< 2021년 7월 기준 구성원 - 총 11명 >
지도교수 - 조재흥 교수님 /정동현(MD7) 손영진(MD5), 최지수(MD5), 박연우(MD5), 김경민(MD4), 김성한(MD4), 이유정(MD4), 이유리(MD3), 선승원(MD2), 김효경(MD1), 유지희(MD1)

26/06/2023
Systematic Electronic Tuning on the Property and Reactivity of Cobalt–(Hydro)peroxo Intermediates 26/06/2023

우리 연구실 학생(김경민)이 first author이고 조재흥 교수님께서 corresponding author인 논문이 Inorganic Chemitry(IF = 5.4)에 Publish 되었습니다. 자세한 내용은 link를 통해서 확인하실 수 있습니다.

Systematic Electronic Tuning on the Property and Reactivity of Cobalt–(Hydro)peroxo Intermediates A series of cobalt(III)–peroxo complexes, [CoIII(R2-TBDAP)(O2)]+ (1R2; R2 = Cl, H, and OMe), and cobalt(III)–hydroperoxo complexes, [CoIII(R2-TBDAP)(O2H)(CH3CN)]2+ (2R2), bearing electronically tuned tetraazamacrocyclic ligands (R2-TBDAP = N,N′-di-tert-butyl-2,11-diaza[3.3](2,6)-p-R2-pyridinop...

Photodynamic treatment of acute vascular occlusion by using an iron–nitrosyl complex 26/06/2023

우리 연구실 학생(최지수)이 first author이고 조재흥 교수님께서 corresponding author인 논문이 Chem(IF = 25.8)에 Publish 되었습니다. 자세한 내용은 link를 통해서 확인하실 수 있습니다.

Photodynamic treatment of acute vascular occlusion by using an iron–nitrosyl complex Retinal vascular occlusion (RVO) is a common cause of visual impairment. Although several approaches, including vasodilators, have been explored to tr…

26/06/2023

우리 연구실 학생(정동현)이 first author이고 조재흥 교수님께서 corresponding author인 논문이 Coordination Chemistry Review(IF = 24.8)에 Publish 되었습니다. 자세한 내용은 link를 통해서 확인하실 수 있습니다.
https://www.sciencedirect.com/science/article/pii/S0010854523000103

Bio-inspired mononuclear nonheme metal peroxo complexes: Synthesis, structures and mechanistic studies toward understanding enzymatic reactions 26/06/2023

우리 연구실 학생(정동현)이 first author이고 조재흥 교수님께서 corresponding author인 논문이 Coordination Chemistry Review(IF = 24.8)에 Publish 되었습니다. 자세한 내용은 link를 통해서 확인하실 수 있습니다.

Bio-inspired mononuclear nonheme metal peroxo complexes: Synthesis, structures and mechanistic studies toward understanding enzymatic reactions Metalloenzymes utilize inexpensive and earth-abundant transition metal ions as important co-factors to enable binding of a dioxygen molecule so that i…

26/06/2023

우리 연구실 학생들(정동현, 김효경)이 first author이고 조재흥 교수님께서 corresponding author인 논문이 Journal of the American Chemical Society(IF = 16.4)에 Publish 되었습니다. 자세한 내용은 link를 통해서 확인하실 수 있습니다.
https://pubs.acs.org/doi/10.1021/jacs.2c09274

Aliphatic and Aromatic C–H Bond Oxidation by High-Valent Manganese(IV)-Hydroxo Species 26/06/2023

우리 연구실 학생(이유정)이 first author이고 조재흥 교수님께서 corresponding author인 논문이 Journal of the American Chemical Society(IF = 16.4)에 Publish 되었습니다. 자세한 내용은 link를 통해서 확인하실 수 있습니다.

Aliphatic and Aromatic C–H Bond Oxidation by High-Valent Manganese(IV)-Hydroxo Species The strong C–H bond activation of hydrocarbons is a difficult reaction in environmental and biological chemistry. Herein, a high-valent manganese(IV)-hydroxo complex, [MnIV(CHDAP-O)(OH)]2+ (2), was synthesized and characterized by various physicochemical measurements, such as ultraviolet–visible...

Structure and Reactivity of Nonporphyrinic Terminal Manganese(IV)–Hydroxide Complexes in the Oxidative Electrophilic Reaction 26/06/2023

우리 연구실 학생들(박연우, 김성한)이 first author이고 조재흥 교수님께서 corresponding author인 논문이 Inorganic Chemistry ( IF = 5.2)에 Publish 되었습니다. 자세한 내용은 link를 통해서 확인하실 수 있습니다.

Structure and Reactivity of Nonporphyrinic Terminal Manganese(IV)–Hydroxide Complexes in the Oxidative Electrophilic Reaction High-valent transition metal–hydroxide complexes have been proposed as essential intermediates in biological and synthetic catalytic reactions. In this work, we report the single-crystal X-ray structure and spectroscopic characteristics of a mononuclear nonporphyrinic MnIV–(OH) complex, [MnIV(Me...

A functional model for quercetin 2,4-dioxygenase: Geometric and electronic structures and reactivity of a nickel(II) flavonolate complex 18/10/2021

우리 연구실 학생들(정동현, 선승원)이 first author이고 조재흥 교수님께서 corresponding author인 논문이 Journal of Inorganic Biochemistry ( IF = 4.2)에 Accepted 되었습니다. 자세한 내용은 link를 통해서 확인하실 수 있습니다. 이 연구는 postech 문도현 박사님과 공동 연구를 통해 진행되었습니다.

A functional model for quercetin 2,4-dioxygenase: Geometric and electronic structures and reactivity of a nickel(II) flavonolate complex Quercetin 2,4-dioyxgenase (QueD) has been known to catalyze the oxygenative degradation of flavonoids and quercetin. Recent crystallographic study rev…

Spectroscopic Evidence for a Cobalt-Bound Peroxyhemiacetal Intermediate 18/10/2021

우리 연구실 학생(손영진)이 1저자이고 조재흥 교수님께서 corresponding author인 논문이 Journal of the American Chemical Society Au (IF=pending)에 Accepted 되었습니다. 자세한 내용은 link를 통해서 확인하실 수 있습니다. 이 연구는 Radboud 대학 Jana Roithová 교수팀과 공동 연구를 통해 진행되었습니다.

Spectroscopic Evidence for a Cobalt-Bound Peroxyhemiacetal Intermediate Aldehyde deformylation reactions by metal dioxygen adducts have been proposed to involve peroxyhemiacetal species as key intermediates. However, direct evidence of such intermediates has not been obtained to date. We report the spectroscopic characterization of a mononuclear cobalt(III)-peroxyhemiac...

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울주군 언양읍 유니스트길 50 (언양읍, 울산과학기술원)
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