21/05/2025
From industrial perspective, Brรธnsted acid catalysts are essential for various organic transformation reactions. Compared to homogeneous acid catalysts, heterogeneous counterparts offer ease of separation and reusability. Organic based, metal-free, crystalline Brรธnsted acid heterocatalysts are rare and difficult to synthesize. Covalent organic frameworks (COFs) with high specific surface area, stability and desired organic functionality, have huge potential as heterogeneous organocatalysts. In this regard, ๐ฆ๐๐ฑ๐ถ๐ฝ and ๐ฆ๐ฎ๐ป๐๐ came up with a -SO3H group attached COF (TFR-TDS-COF). The crystallinity along with high NH3 uptake capacity (acidity) of the material, facilitated various acid-catalyzed organic reactions like amination of epoxides, cycloaddition and acetalization reactions, with excellent conversion and selectivity.
Check out this article published in ๐๐ฑ๐๐ฎ๐ป๐ฐ๐ฒ๐ฑ ๐ฆ๐๐๐๐ฎ๐ถ๐ป๐ฎ๐ฏ๐น๐ฒ ๐ฆ๐๐๐๐ฒ๐บ๐.
https://advanced.onlinelibrary.wiley.com/doi/10.1002/adsu.202500069?s=08