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Kaushal Jain Chemistry

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Kaushal Jain Chemistry

Chemistry faculty at Allen career institute

18/07/2020

Important Update
Due to partial cancellation of exams by many Education Boards.
JAB (Joined Admission Board) has announced that aspirants will be eligible for admission to irrespective of marks obtained in Class 12th.

14/05/2020

PINACOL REARRANGEMENT
~is actually a type of an E1 elimination, although we rarely look at it from such perspective.
So, once you protonate one of the OH groups and form a leaving group, you’ll get a carbocation formation. In the example I have shown above, we get a tertiary carbocation. So, why would it rearrange further? 🤔 Simple—you’ll get a resonancely stabilized carbocation with a partial C=O bond character. And as the C=O bond is very thermodynamically stable, it will drive the rearrangement.

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