26/09/2015
Forming Ionic Compounds
Knowing the oxidation number of a
compound is very important when
discussing ionic compounds. Ionic
compounds are combinations of
positive and negative ions. They are
generally formed when nonmetals and
metals bond. To determine which
substance is formed, we must use the
charges of the ions involved. To make
a neutral molecule, the positive charge
of the cation (positively-charged ion)
must equal the negative charge of the
anion (negatively-charged ion). In
order to create a neutral charged
molecule, you must combine the
atoms in certain proportions. Scientists
use subscripts to identify how many of
each atom makes up the molecule. For
example, when combining magnesium
and nitrogen we know that the
magnesium ion has a "+2" charge and
the nitrogen ion has a "-3" charge. To
cancel these charges, we must have
three magnesium atoms for every two
nitrogen atoms:
3Mg2+ + 2N3- --> Mg3N2
Knowledge of the charges of ions is
crucial to knowing the formulas of the
compounds formed.
alkalis (1st column elements) form
"+1" ions such as Na+ and Li+
alkaline earth metals (2nd column
elements) form "2+" ions such as
Mg2+ and Ba2+
halogens (7th column elements) form
"-1" ions such as Cl- and I-
Other common ions are listed in the
table below:
Positive ions (cations) Negative ions (anions)
1+ 1-
ammonium (NH4+) acetate (C2H3O2-)
copper(I) (Cu+) azide (N3-)
hydrogen (H+) chlorate (ClO3-)
silver (Ag+) cyanide (CN-)
dihydrogen phosphate (H2PO4-)
2+ hydride (H-)
cadmium (Cd2+) bicarbonate (HCO3-)
cobalt(II) (Co2+) hydroxide (OH-)
copper(II) (Cu2+) nitrate (NO3-)
iron (Fe2+) nitrite (NO2-)
lead (Pb2+) perchlorate (ClO4-)
manganese(II) (Mn2+) permanganate (MnO4-)
mercury(I) (Hg22+) thiocyanate(SCN-)
mercury(II) (Hg2+)
nickel (Ni2+) 2-
tin (Sn2+) carbonate (CO32-)
zinc (Zn2+) chromate (CrO42-)
dichromate (Cr2O72-)
3+ hydrogen phosphate (HPO42-)
aluminum (Al3+) oxide (O2-)
chromium(III) (Cr3+) peroxide (O22-)
iron(III) (Fe3+) sulfate (SO42-)
sulfide (S2-)
sulfite (SO32-)
3-
nitride (N3-)
phosphate (PO43-)
phosphide (P3-)