30/09/2024
Nice work of Campinas Electrochemistry Group - PSF in collaboration with Angel Cuesta.
Long story short.
-We got inspired by this nice paper by Markovic and col: https://www.nature.com/articles/nchem.330
- We got several microscopic insights by performing FTIR in situ in the ATR mode.
- Among other findings, we got a rational and logical explanation for the cation-induced differences in activities in the voltammetric profiles for several alcohols and polyols.
- Take a look here: https://pubs.acs.org/doi/10.1021/jacs.4c09590
Center for Innovation on New Energies
Instituto de Química - Unicamp
Rafael Vicente
The activity of Pt for the electro-oxidation of several organic molecules changes with the cation of the electrolyte. It has been proposed that the underlying reason behind that effect is the so-called noncovalent interactions between the hydrated cations and adsorbed OH (OHad). However, there is a....