25/09/2026
🧪 **Hybridization & Molecular Geometry**: **Hybridization** is the mixing of atomic orbitals of comparable energy to form equivalent **hybrid orbitals**, which help explain molecular shape and bonding. Molecular geometry depends mainly on the number of **bond pairs and lone pairs** around the central atom according to VSEPR theory.
📌 **Key Examples:**
• **sp → Linear → BeCl₂ → 180°**
• **sp² → Trigonal planar → BF₃ → 120°**
• **sp³ → Tetrahedral → CH₄ → 109.5°**
• **sp³ → Trigonal pyramidal → NH₃ → 107°**
• **sp³ → Bent → H₂O → 104.5°**
• **sp³d → Trigonal bipyramidal → PCl₅ → 90°, 120°**
• **sp³d² → Octahedral → SF₆ → 90°**
🔑 **Remember:** Lone pairs occupy more space than bond pairs and generally **decrease bond angles**.